After it has been run and stood over night pull the plugs out to see if any have gone rusty. If they are numbers 1,2,7,8 could be head gasket or cracked block / slipped liner. If either numbers 3,4,5,6 are rusty its definately the cracked block / slipped liner, as there is no water running around the heads on these cylinders.
I had a 4.6 range rover and it just went with no warning, same as yours travel 2 miles and it boiled. I got through 2 engines with this.
Good luck
Mark