From what I read, there seems to be significant differences in quality between even commercially produced biodiesel, some of which is very bad indeed. A simple test for quality is to mix equal volumes of biodiesel with water in a jar and give it a good shake. The two layers should separate quite quickly, leaving a cloudy but separate diesel layer and a very slightly milky water layer. If you get a thick band in between which doesn't separate, or even worse, a thick emulsion, you know you will have problems, either due to formation of soaps, incomplete transesterification, or insufficient washing.