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Is it a petrol or a diesel? If diesel then it's likely to be low temperature stopping the fuel being burnt, faulty glow plugs would be a place to start or the pre-heat system. Could also be condensation in the exhaust, you should be able to tell if it's steam or diesel by the smell.

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White smoke at cold diesel engine start is common as per Ratty43 post.

In that case it is unburnt fuel. Unburnt diesel from a warm engine could occur if compression is poor or injectors aren't atomising properly.

White smoke can also be water vapour - leaking gasket or cracked head.

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